Formation of dimethylamine complexes of trimethylplatinum(IV) from reactions with N,N,N’,N’-tetramethyldiaminomethane

Abel, Edward W; Goldsworthy, Duncan H; Heard, Peter J and Kite, Kenneth (1995) Formation of dimethylamine complexes of trimethylplatinum(IV) from reactions with N,N,N’,N’-tetramethyldiaminomethane.

View this record at http://dx.doi.org/10.1016/0277-5387(94)00268-J

Abstract

Attempts to prepare complexes of trimethylplatinum(IV) with N,N,N′N′-tetramethyldiaminomethane (TMDM) as either a chelating or bridging ligand gave only the complexes of dimethylamine [PtMe₃X(HNMe₂))]₂(X = Cl, Br and I ; 1–3 and [PtMe₃((2,2′-bipyridyil) (HNMe₂))]⁺[[BF₄]]⁺ (4)). ¹HH NMR evidence showed that only one of the two possible isomers was formed for 1–3.

Item Type: Article
Additional Information: Copyright © 1995 Published by Elsevier Ltd. Only metadata available from this website. This article was originally published in the Polyhedron Journal in 2003 by Elsevier, the full article can be found at http://dx.doi.org/10.1016/0277-5387(94)00268-J
Keywords: Trimethylplatinum(IV) complexes, dimethylamine complxes, tetramethyldiaminomethane
Members: Glyndŵr University
Depositing User: ULCC Admin
Date Deposited: 05 Oct 2011 09:13
Last Modified: 20 Mar 2016 21:19
URI: http://collections.crest.ac.uk/id/eprint/143

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